Efficient synthesis of multisubstituted 2-alkenylpyridines via 2,3-rearrangement of O-homoallenylic oximes
Author:
Affiliation:
1. Research and Analytical Center for Giant Molecules
2. Graduate School of Science
3. Tohoku University
4. Sendai 980-8578
5. Japan
6. Department of Chemistry
Abstract
O-Homoallenylic α,β-unsaturated oximes were efficiently converted to the corresponding 2-alkenylpyridine derivatives by microwave irradiation.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00703A
Reference26 articles.
1. [2,3] [3,3]: the novel [2,3] sigmatropic rearrangement of oxime-o-allyl ethers
2. Palladium (II) catalysed tandem [2,3]-sigmatropic shift-1,3-dipolar cycloaddition processes in oxime O-allyl ethers
3. Thermally-induced skeletal rearrangement of (Z)-O-propargylic α,β-unsaturated aldoximes to multisubstituted pyridine oxides
4. Copper-Catalyzed Tandem [2,3]-Rearrangement and 6π-3-Azatriene Electrocyclization in (E)-O-Propargylic α,β-Unsaturated Oximes
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