Halogenated MOF-5 variants show new configuration, tunable band gaps and enhanced optical response in the visible and near infrared-Reference-Cited by-同舟云学术

Halogenated MOF-5 variants show new configuration, tunable band gaps and enhanced optical response in the visible and near infrared

Published:2016 Issue:47 Volume:18 Page:32319-32330
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Yang Li-Ming¹²³⁴,Fang Guo-Yong¹⁵⁶⁷^ORCID,Ma Jing¹⁵⁶⁷,Pushpa Raghani⁸⁹¹⁰¹¹,Ganz Eric⁸¹²¹³¹¹

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Huazhong University of Science and Technology

3. Wuhan 430074

4. China

5. Nanjing University

6. Nanjing

7. P. R. China

8. Department of Physics

9. Boise State University

10. Boise

11. USA

12. University of Minnesota

13. Minneapolis

Abstract

We show that full halogenation of paradigm MOF-5 can tune the band gap and optical response between 1.0 and 4.2 eV leading to optical activity in the visible and infrared. Applications include photocatalysts, photoactive materials, and optoelectronics.

Funder

Huazhong University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP06981A

Reference91 articles.

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2. Chem. Rev., 2012, 112, special issue on MOFs

3. Novel Photocatalysts for the Decomposition of Organic Dyes Based on Metal-Organic Framework Compounds