Multi-substituted trifluoromethyl alkene construction <i>via</i> gold-catalyzed fluoroarylation of <i>gem</i>-difluoroallenes-Reference-Cited by-同舟云学术

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Multi-substituted trifluoromethyl alkene construction via gold-catalyzed fluoroarylation of gem-difluoroallenes

Published:2024 Issue:10 Volume:15 Page:3524-3529
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Zhi-Qiang¹,Tang Hai-Jun¹,Wang Zaixin¹,Wang Cheng-Qiang¹,Feng Chao¹^ORCID

Affiliation:

1. Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816, P. R. China

Abstract

A visible-light-promoted gold-catalyzed fluoroarylation of gem-difluoroallenes is developed. This reaction proceeds in a highly stereo- and regioselective manner and enables a facile construction of tri- and tetra-substituted trifluoromethyl alkenes.

Funder

National Natural Science Foundation of China

Government of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06060H

Reference50 articles.

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2. G.Haufe and F. R.Leroux , Fluorine in Life Sciences: Pharmaceutical, Medicinal Diagnostics, and Agrochemicals , Elsevier , Amsterdam , 2019

3. The fluorinated natural products

4. Current Contributions of Organofluorine Compounds to the Agrochemical Industry

5. Where Does the Fluorine Come From? A Review on the Challenges Associated with the Synthesis of Organofluorine Compounds

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