CC-stretched formic acid: isomerisation, dimerisation, and carboxylic acid complexation-Reference-Cited by-同舟云学术

CC-stretched formic acid: isomerisation, dimerisation, and carboxylic acid complexation

Published:2021 Issue:32 Volume:23 Page:17208-17223
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Meyer Katharina A. E.¹^ORCID,Nejad Arman¹^ORCID

Affiliation:

1. Institute of Physical Chemistry, University of Göttingen, Tammannstr. 6, 37077 Göttingen, Germany

Abstract

The cis–trans-isomerism of the propiolic acid monomer (HCC–COOH) is examined with linear Raman jet spectroscopy, yielding the first environment-free vibrational band centres of a higher-energy cis-rotamer beyond formic acid (HCOOH) in addition to all fundamentals and a large number of hot and combination/overtone bands of the trans-conformer.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02700J

Reference87 articles.

1. Communication: The highest frequency hydrogen bond vibration and an experimental value for the dissociation energy of formic acid dimer

2. Concerted Hydrogen Exchange Tunneling in Formic Acid Dimer

3. High-Resolution Infrared Spectroscopy of the Formic Acid Dimer