The synthesis, chain-packing simulation and long-term gas permeability of highly selective spirobifluorene-based polymers of intrinsic microporosity

Author:

Bezzu C. Grazia12345ORCID,Carta Mariolino67895ORCID,Ferrari Maria-Chiara101112135,Jansen Johannes C.141516ORCID,Monteleone Marcello141516ORCID,Esposito Elisa141516ORCID,Fuoco Alessio141516ORCID,Hart Kyle17181920ORCID,Liyana-Arachchi T. P.21222320,Colina Coray M.21222320ORCID,McKeown Neil B.12345ORCID

Affiliation:

1. EaStCHEM

2. School of Chemistry

3. University of Edinburgh

4. Edinburgh

5. UK

6. Department of Chemistry

7. Swansea University

8. College of Science

9. Swansea

10. Institute for Materials and Processes

11. School of Engineering

12. The University of Edinburgh

13. Edinburgh EH9 3JL

14. Institute on Membrane Technology

15. ITM-CNR

16. Italy

17. Department of Materials Science and Engineering

18. The Pennsylvania State University

19. University Park

20. USA

21. Center for Macromolecular Science and Engineering

22. University of Florida

23. Gainesville

Abstract

Methyl or t-butyl substituted spirobifluorenes greatly enhance PIM permeability.

Funder

Engineering and Physical Sciences Research Council

Seventh Framework Programme

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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