A novel symmetric pyrazine (pyz)-bridged uranyl dimer [UO2Cl3(H2O)(Pyz)0.5]22−: synthesis, structure and computational analysis-Reference-Cited by-同舟云学术

A novel symmetric pyrazine (pyz)-bridged uranyl dimer [UO₂Cl₃(H₂O)(Pyz)_0.5]₂²⁻: synthesis, structure and computational analysis

Published:2022 Issue:29 Volume:51 Page:11013-11020
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Byrne Nicole M.¹^ORCID,Schofield Mark H.¹^ORCID,Cahill Christopher L.¹^ORCID

Affiliation:

1. Department of Chemistry, The George Washington University, 800 22nd St NW, Suite 4000, Washington, D.C., 20052, USA

Abstract

Characterization of the pyrazine-bridged uranyl dimer of (HPyz+)2[UO2Cl3(H2O)(Pyz)0.5]2·2H2O, featuring a delocalized π-system and stronger UO bonds than those present in the more typically observed [UO2Cl4]2− monomer.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01486F

Reference38 articles.

1. Restricted Speciation and Supramolecular Assembly in the 5f Block

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4. The uranyl tetrachloride anion as a tecton in the assembly of U(VI) hybrid materials

5. Synthesis and spectroscopic characterization of actinyl(VI) tetrahalide coordination compounds containing 2, 2′-bipyridine

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