Between carbide and nitride MAX phases: sol–gel assisted synthesis and characterization of the carbonitride phase Cr2GaC1−xNx

Author:

Kubitza Niels1,Huck Isabel1,Pazniak Hanna2,Kalha Curran3,Koch David4,Zhao Bo4,Thakur Pardeep K.5ORCID,Lee Tien-Lin5,Riaz Aysha A.3,Donner Wolfgang4,Zhang Hongbin4,Moss Benjamin6,Wiedwald Ulf2ORCID,Regoutz Anna3ORCID,Birkel Christina S.17ORCID

Affiliation:

1. Department of Chemistry, Technische Universität Darmstadt, Germany

2. Faculty of Physics and Center for Nanointegration Duisburg-Essen, University of Duisburg-Essen, Germany

3. Department of Chemistry, University College London, London, WC1H 0AJ, UK

4. Institute of Materials Science, Technische Universität Darmstadt, 64287 Darmstadt, Germany

5. Diamond House, Harwell Science and Innovation Campus, Fermi Ave, Didcot, OX11 0DE, UK

6. Department of Chemistry, Molecular Science Research Hub, White City Campus, Imperial College London, London W12 0BZ, UK

7. School of Molecular Sciences, Arizona State University, Tempe AZ-85282, USA

Abstract

The combination of a sol–gel precursor approach and microwave heating leads to a hitherto unknown MAX phase Cr2GaC1−xNx. Magnetic measurements reveal that the susceptibility depends on the nitrogen amount on the X-site.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

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