Mixed valency in a neutral 1D Fe-chloranilate coordination polymer

Author:

Clutterbuck Katelyn M.1ORCID,Abrahams Brendan F.1ORCID,Hudson Timothy A.1,van Koeverden Martin P.1ORCID

Affiliation:

1. School of Chemistry, University of Melbourne, Parkville, Victoria 3010, Australia

Abstract

A neutral Fe-chloranilate chain, with triphenylphosphine oxide co-ligands, represents a rare example of a one-dimensional chain in which there is a temperature dependent electron transfer from the Fe(ii) centre to the bridging chloranilate ligand.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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