Synthesis of N-alkoxy amines and hydroxylamines via the iridium-catalyzed transfer hydrogenation of oximes

Author:

Xia Yanping1,Wang Sen1,Miao Rui1,Liao Jianhua21ORCID,Ouyang Lu1,Luo Renshi12ORCID

Affiliation:

1. School of Pharmaceutical Sciences, Gannan Medical University, Ganzhou, Jiangxi Province, P. R. China

2. College of Chemistry and Environmental Engineering, Shaoguan University, Shaoguan 512005, China

Abstract

An efficient and practical strategy for the construction of N-alkoxy amines and hydroxylamines through the corresponding oximes is described via an Ir-catalyzed acid-assisted system with high yields and a good substrate scope.

Funder

National Natural Science Foundation of China

Jiangxi Provincial Department of Science and Technology

Gannan Medical University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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