Synthesis and electronic coupling studies of cyclometalated diruthenium complexes bridged by 3,3′,5,5′-tetrakis(benzimidazol-2-yl)-biphenyl-Reference-Cited by-同舟云学术

Synthesis and electronic coupling studies of cyclometalated diruthenium complexes bridged by 3,3′,5,5′-tetrakis(benzimidazol-2-yl)-biphenyl

Published:2021 Issue:12 Volume:50 Page:4219-4230
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Hao¹²³⁴⁵,Shao Jiang-Yang⁶⁷⁸⁹¹⁰^ORCID,Duan Ran⁶⁷⁸⁹¹⁰,Wang Ke-Zhi¹²³⁴⁵^ORCID,Zhong Yu-Wu⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Beijing Key Laboratory of Energy Conversion and Storage Materials

2. College of Chemistry

3. Beijing Normal University

4. Beijing 100875

5. China

6. Beijing National Laboratory for Molecular Sciences

7. CAS Key Laboratory of Photochemistry

8. CAS Research/Education Center for Excellence in Molecular Sciences

9. Institute of Chemistry

10. Chinese Academy of Sciences

Abstract

Electrochemical and intervalence charge-transfer studies suggest that when the same or similar terminal ligands are used, the strength of the bridging ligand in mediating the Ru–Ru coupling decreases in the order of tpbp > H-tbibp > Me-tbibp.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Beijing Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00263E

Reference71 articles.

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4. Mixed valency in ligand-bridged diruthenium frameworks: divergences and perspectives

5. Electrostatic interactions within mixed-valent compounds

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