Promotion of 1,3-dipolar cycloaddition between azides and β-enaminones by deep eutectic solvents
Author:
Affiliation:
1. Núcleo de Química de Heterociclos (NUQUIMHE)
2. Departamento de Química
3. Universidade Federal de Santa Maria
4. 97105-900 Santa Maria
5. Brazil
Abstract
The metal-free, high selectivity and efficient synthesis of 4-acyl triazoles in a DES (ChCl:ethylene glycol) is reported.
Funder
Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul
Conselho Nacional de Desenvolvimento Científico e Tecnológico
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C5NJ03654B
Reference32 articles.
1. R. Huisgen , Proceedings of the Chemical Society, London, 1961, p. 357
2. 1,3-Dipolar Cycloaddition Chemistry, ed. R. Huisgen and A. Pawda, Wiley, New York, 1984, p. 1
3. Kinetics and reaction mechanisms: selected examples from the experience of forty years
4. Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides
5. A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes
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