Comparing London dispersion pnictogen–π interactions in naphthyl-substituted dipnictanes-Reference-Cited by-同舟云学术

Comparing London dispersion pnictogen–π interactions in naphthyl-substituted dipnictanes

Published:2022 Issue:13 Volume:51 Page:5016-5023
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gehlhaar Alexander¹,Schiavo Eduardo²^ORCID,Wölper Christoph¹,Schulte Yannick¹,Auer Alexander A.²,Schulz Stephan¹³^ORCID

Affiliation:

1. Institute for Inorganic Chemistry, University of Duisburg-Essen, Universitätsstraße 5-7, D-45117 Essen, Germany

2. Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim an der Ruhr, Germany

3. Center for Nanointegration Duisburg-Essen (Cenide), University of Duisburg-Essen, Germany

Abstract

The importance of London dispersion in heavy main group element chemistry is demonstrated for naphthyl-substituted dipnictanes using a combination of X-ray diffraction and quantum chemistry.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00477A

Reference46 articles.

1. Overcoming lability of extremely long alkane carbon–carbon bonds through dispersion forces

2. An Update on Multiple Bonding between Heavier Main Group Elements: The Importance of Pauli Repulsion, Charge-Shift Character, and London Dispersion Force Effects

3. London dispersion forces in sterically crowded inorganic and organometallic molecules

4. Strong Closed-Shell Interactions in Inorganic Chemistry

5. Dispersion Forces Drive the Formation of Uranium–Alkane Adducts

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