Cobalt nanoclusters coated with N-doped carbon for chemoselective nitroarene hydrogenation and tandem reactions in water

Author:

Gutiérrez-Tarriño Silvia1234ORCID,Rojas-Buzo Sergio1234ORCID,Lopes Christian W.567ORCID,Agostini Giovanni894ORCID,Calvino Jose. J.101112134ORCID,Corma Avelino1234ORCID,Oña-Burgos Pascual123414ORCID

Affiliation:

1. Instituto de Tecnología Química

2. Universitat Politècnica de València-Consejo Superior de Investigaciones Científicas (UPV-CSIC)

3. 46022 Valencia

4. Spain

5. Institute of Chemistry

6. Universidade Federal do Rio Grande do Sul – UFRGS

7. Brazil

8. CELLS-ALBA Synchrotron Radiation Facility

9. Barcelona

10. Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica

11. Facultad de Ciencias

12. Universidad de Cádiz

13. Cádiz

14. Department of Chemistry and Physics

Abstract

Subnanometric cobalt nanoclusters covered by N-doped carbon layers (Co@NC-800) catalyze the chemoselective reduction of nitroarenes and the one-pot synthesis of secondary aryl amines and isoindolinones in aquo media under mild reaction conditions.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Agência Nacional do Petróleo, Gás Natural e Biocombustíveis

Universitat Politècnica de València

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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