Nucleophilic catalysis of p-substituted aniline derivatives in acylhydrazone formation and exchange-Reference-Cited by-同舟云学术

Nucleophilic catalysis of p-substituted aniline derivatives in acylhydrazone formation and exchange

Published:2021 Issue:33 Volume:19 Page:7202-7210
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Canal-Martín Andrea¹,Navo Claudio D.²^ORCID,Sáez Elena³,Molero Dolores³,Jiménez-Osés Gonzalo²⁴^ORCID,Pérez-Fernández Ruth¹^ORCID

Affiliation:

1. Structural and Chemical Biology Department, Centro de Investigaciones Biológicas Margarita Salas, CIB-CSIC, Madrid 28040, Spain

2. Center for Cooperative Research in Biosciences (CIC bioGUNE), Basque Research and Technology Alliance (BRTA), Bizkaia Technology Park, Building 800, 48160 Derio, Spain

3. CAI de RMN, Universidad Complutense de Madrid, 28040 Madrid, Spain

4. Ikerbasque, Basque Foundation for Science, 48013 Bilbao, Spain

Abstract

Mechanistic study and superior performance of electron-rich p-substituted aniline derivatives as catalysts for efficient hydrazone formation and exchange in both protic and aprotic solvents.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00871D

Reference56 articles.

1. Bioorthogonal Chemistry: Fishing for Selectivity in a Sea of Functionality

2. Oximes and Hydrazones in Bioconjugation: Mechanism and Catalysis

3. The Controlled Display of Biomolecules on Nanoparticles: A Challenge Suited to Bioorthogonal Chemistry

4. Oxime formation for fluorine-18 labeling of peptides and proteins for positron emission tomography (PET) imaging: A review

5. Simple Hydrazone Building Blocks for Complicated Functional Materials

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