Thermodynamically driven self-assembly of pyridinearene to hexameric capsules

Author:

Kiesilä Anniina123ORCID,Beyeh Ngong Kodiah4156ORCID,Moilanen Jani O.123ORCID,Puttreddy Rakesh123ORCID,Götz Sven7891011,Rissanen Kari123ORCID,Barran Perdita1213141516ORCID,Lützen Arne7891011ORCID,Kalenius Elina123ORCID

Affiliation:

1. Department of Chemistry

2. Nanoscience Center

3. Finland

4. Oakland University

5. Rochester

6. USA

7. University of Bonn

8. Kekulé-Institute of Organic Chemistry and Biochemistry

9. A

10. D-53121 Bonn

11. Germany

12. Michael Barber Centre for Collaborative Mass Spectrometry

13. Manchester Institute of Biotechnology

14. School of Chemistry

15. The University of Manchester

16. Manchester

Abstract

For the first time the formation of hexameric pyridine[4]arene capsule has been observed in gas phase, in solution and in solid state. A thermodynamic balance between capsule formation was observed, showing favour to hexamer.

Funder

Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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