Lithium and magnesium complexes by using pyridyl-pendanted unsymmetrical β-diketiminates: syntheses and application as catalysts for the hydroboration of carbonyl compounds

Author:

Li Yafei1,Pan Huifen1,Lu Yanhua1,Luo Yanshu2,Dang Yan1,Wang Yalan1,Xia Shengwang1,Li Yahong1ORCID,Xia Yuanzhi2ORCID

Affiliation:

1. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

2. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China

Abstract

Two lithium and one magnesium complexes supported by pyridyl-pendanted unsymmetrical β-diketiminates have been synthesized and characterized. They showed high catalytic activity for the hydroboration of aldehydes and ketones.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Priority Academic Program Development of Jiangsu Higher Education Institutions

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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