Facile C–H bond activation on a transient gallium imide-Reference-Cited by-同舟云学术

Facile C–H bond activation on a transient gallium imide

Published:2022 Issue:49 Volume:58 Page:6946-6949
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kassymbek Aishabibi¹,Spasyuk Denis²,Dmitrienko Anton¹,Pilkington Melanie¹^ORCID,Nikonov Georgii I.¹^ORCID

Affiliation:

1. Department of Chemistry, Brock University, 1812 Sir Isaac Brock Way, St. Catharines, Ontario, L2S 3A1, Canada

2. Canadian Light Source Inc., 44 Innovation Blvd., Saskatoon, Saskatchewan, S7N 2V3, Canada

Abstract

In situ imidation of the Ga(i) compound 1 by azide N3SiMe3 results in transient monomeric imide NacNacGaNSiMe3 amenable to C–H bond activation of a variety of substrates featuring hard donor sites.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01857H

Reference39 articles.

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5. New approaches to the generation of phosphinidenes

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2. Reactions of Low-Valent Gallium Species with Organic Azides: Formation of Imido-, Azoimido-, and Tetrazene Complexes;Inorganic Chemistry;2023-04-10

3. Reactions of main group compounds with azides forming organic nitrogen-containing species;Chemical Society Reviews;2023

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