Synthesis of bis[palladium(ii)] and bis[platinum(ii)] complexes containing chiral, linear quadridentate ligands with a P2N2 donor set
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2002/DT/B106861J
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2. Preparation and Stereochemistry of Cobalt(III) Complexes Containing 3,6-Diphenyl-3,6-diphosphaoctane-1,8-diamine or (2S,9S)-4,7-Diphenyl-4,7-diphosphadecane-2,9-diamine, NH2CHRCH2P(C6H5)CH2CH2P(C6H5)CH2CHRNH2(R=H, CH3)
3. Transition metal-mediated discrimination between diastereoisomers of a new linear P2N2ligand, L1; X-ray structure analysis of rac-L1, [Pt(rac-L1)Cl]Cl·2H2O, and an unusual RhIdimer [Rh2(rac-L1–H)2(CO)2]·2H2O
4. Synthesis of a new P2N2ligand N,N′-bis[2-(diphenylphosphino)phenyl]propane-1,3-diamine, H2L2, and some of its complexes with elements of the nickel triad and rhodium: X-ray structure analyses of the neutral complex [NiL2] and the trans-spanned [Rh(CO)Cl(H2L2)]
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