Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(i) dimers-Reference-Cited by-同舟云学术

Synthesis, structural and photophysical properties of dimethylphosphino(perfluoro-)phenylene-based gold(i) dimers

Published:2022 Issue:5 Volume:51 Page:1955-1967
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Müller Felix¹^ORCID,Wickemeyer Lucas¹^ORCID,Schwabedissen Jan¹^ORCID,Ertl Martin²,Neumann Beate¹,Stammler Hans-Georg¹^ORCID,Monkowius Uwe²^ORCID,Mitzel Norbert W.¹^ORCID

Affiliation:

1. Lehrstuhl für Anorganische Chemie und Strukturchemie; Centrum für Molekulare Materialien CM2, Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, D-33615 Bielefeld, Germany

2. School of Education, Chemistry, Johannes Kepler University Linz, Altenbergerstr. 69, A-4040 Linz, Austria

Abstract

Driven by different weak non-covalent interactions [Au2(μ2-C6H4PMe2)2] and its aryl-perfluorinated analogue aggregate vastly differently in the solid state: the non-fluorinated prefers aurophilic interactions, the fluorinated aryl–aryl interactions.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03658K

Reference72 articles.

1. Aurophilic interactions as a subject of current research: an up-date

2. “Aurophilicity” as a Consequence of Relativistic Effects: The Hexakis(triphenylphosphaneaurio)methane Dication[(Ph3PAu)6C]2⊕

3. Weak Intramolecular Bonding Relationships: The Conformation-Determining Attractive Interaction between Gold(I) Centers