Open-air green-light-driven ATRP enabled by dual photoredox/copper catalysis

Author:

Szczepaniak Grzegorz12ORCID,Jeong Jaepil1ORCID,Kapil Kriti1,Dadashi-Silab Sajjad1ORCID,Yerneni Saigopalakrishna S.3,Ratajczyk Paulina14ORCID,Lathwal Sushil1,Schild Dirk J.1ORCID,Das Subha R.15ORCID,Matyjaszewski Krzysztof1ORCID

Affiliation:

1. Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA

2. Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland

3. Department of Biomedical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA

4. Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland

5. Center for Nucleic Acids Science & Technology, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA

Abstract

Fully oxygen-tolerant photoinduced atom transfer radical polymerization (photo-ATRP) allowed the synthesis of well-defined polymers using a Cu catalyst and eosin Y at ppm levels in both aqueous and organic media.

Funder

Kosciuszko Foundation

National Science Foundation

Ministerstwo Edukacji i Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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