Cobalt-catalyzed intermolecular hydroacylation of aldehydes: initiation of hydride transfer enables turnover
Author:
Affiliation:
1. Key Laboratory of Green Process and Engineering
2. Beijing Key Laboratory of Ionic Liquids Clean Process
3. State Key Laboratory of Multiphase Complex Systems
4. Institute of Process Engineering
5. Chinese Academy of Sciences
Abstract
Intermolecular hydroacylation of aldehydes catalyzed by a low-valent cobalt system was developed. Mechanistic studies disclosed that the rate of the insertion step is significantly promoted in the presence of iPr2NEt, which functions as an initiator of hydride transfer.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00337H
Reference57 articles.
1. Cobalt-Catalyzed C–H Activation
2. Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization
3. Cobalt Catalysis Involving π Components in Organic Synthesis
4. Iron-, Cobalt-, and Nickel-Catalyzed Asymmetric Transfer Hydrogenation and Asymmetric Hydrogenation of Ketones
5. Recent advances in transition metal-catalysed hydroacylation of alkenes and alkynes
Cited by 10 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Part III References;Carbonyl Compounds;2021-08-13
2. Cobalt-Catalyzed Chemoselective Transfer Hydrogenative Cyclization Cascade of Enone-Tethered Aldehydes;Organic Letters;2021-05-07
3. Selective oxidation of alcohol-d1 to aldehyde-d1 using MnO2;RSC Advances;2021
4. Ruthenium-catalysed chemoselective alkylation of nitroarenes with alkanols;Organic Chemistry Frontiers;2021
5. Synthesis of 3‐Unsubstituted Phthalides from Aryl Amides and Paraformaldehyde via Ruthenium(II)‐Catalyzed C–H Activation;European Journal of Organic Chemistry;2020-09-24
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3