Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions

Author:

Cabrero-Antonino Jose R.123ORCID,Adam Rosa123,Papa Veronica123ORCID,Holsten Mattes123,Junge Kathrin123ORCID,Beller Matthias123ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock

2. 18059 Rostock

3. Germany

Abstract

The first general and efficient non-noble metal-catalysed reductive C2-alkoxylation of cyclic imides (phthalimides and succinimides) is presented. Crucial for the success is the use of [Co(BF4)2·6H2O/triphos (L1)] combination and no external additives are required.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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