Photoredox chromium and cobalt dual catalysis for carbonyl allylation with butadiene <i>via</i> allyl radical intermediates-Reference-Cited by-同舟云学术

Photoredox chromium and cobalt dual catalysis for carbonyl allylation with butadiene via allyl radical intermediates

Published:2024 Issue:3 Volume:11 Page:684-689
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Yan Huaipu¹,Zhang Dandan¹,Liu Yonghong¹,Wang Xin¹,Wu Zhixian¹,Jin Yunhe¹^ORCID,Ding Xiaobo²,Shan Jing-Ran³,Hao Erjun²^ORCID,Shi Lei¹²^ORCID

Affiliation:

1. School of Chemistry, Dalian University of Technology, 116024, Dalian, China

2. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, 453007, China

3. Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, California 90095, USA

Abstract

The allylation of aldehydes with dienes was achieved using cobalt and chromium catalysts through a metal-hydride hydrogen atom transfer (MHAT) pathway. The novel reaction resulted in the formation of various homo-allyl alcohols with excellent diastereoselectivity.

Funder

National Natural Science Foundation of China

Henan Normal University

Natural Science Foundation of Henan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D3QO01403G

Reference40 articles.

1. Stereochemical Control via Chirality Pairing: Stereodivergent Syntheses of Enantioenriched Homoallylic Alcohols