Protonation and electrochemical properties of a bisphosphide diiron hexacarbonyl complex bearing amino groups on the phosphide bridge
Author:
Affiliation:
1. Department of Chemistry
2. Graduate School of Science
3. Hiroshima University
4. Higashi-hiroshima 739-8526
5. Japan
6. Department of Earth and Environmental Science
7. University of Milano-Bicocca
8. Milan
9. Italy
Abstract
A bisphosphide-bridged diiron hexacarbonyl complex with NEt2 groups on the phosphide bridge was synthesized to examine a new proton relay system.
Funder
Ministry of Education, Culture, Sports, Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03427G
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5. Electronic and molecular structure relations in diiron compounds mimicking the [FeFe]-hydrogenase active site studied by X-ray spectroscopy and quantum chemistry
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