Symmetry breaking of the bending mode of CO2 in the presence of Ar
Author:
Affiliation:
1. Department of Physics and Astronomy
2. University of Calgary
3. Calgary
4. Canada
5. National Research Council of Canada
6. Ottawa
Abstract
The weak infrared spectrum of CO2–Ar corresponding to the (0111) ← (0110) hot band of CO2 is detected in the region of the carbon dioxide ν3 fundamental vibration, using a tunable OPO laser source to probe a pulsed supersonic slit jet expansion.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02674C
Reference27 articles.
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3. Determination of the structure of ArCO2by radio frequency and microwave spectroscopy
4. Erratum: Determination of the structure of ArCO2 by radiofrequency and microwave spectroscopy [J. Chem. Phys. 70, 4095 (1979)]
5. Optothermal‐infrared and pulsed‐nozzle Fourier‐transform microwave spectroscopy of rare gas–CO2complexes
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