Oxygen transfer reactivity mediated by nickel perfluoroalkyl complexes using molecular oxygen as a terminal oxidant-Reference-Cited by-同舟云学术

Oxygen transfer reactivity mediated by nickel perfluoroalkyl complexes using molecular oxygen as a terminal oxidant

Published:2023 Issue:25 Volume:14 Page:7026-7035
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Deolka Shubham¹^ORCID,Govindarajan R.¹^ORCID,Khaskin Eugene¹^ORCID,Vasylevskyi Serhii¹^ORCID,Bahri Janet¹^ORCID,Fayzullin Robert R.²^ORCID,Roy Michael C.¹,Khusnutdinova Julia R.¹^ORCID

Affiliation:

1. Coordination Chemistry and Catalysis Unit Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, 904-0495, Okinawa, Japan

2. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 8 Arbuzov Street, Kazan, 420088, Russian Federation

Abstract

Aerobic oxidation of long-chain perfluoroalkyl Ni complexes results in O-atom transfer to form perfluorocarboxylates via high valent Ni; in the presence of external substrate, oxygenation of phosphines, sulfides, stilbenes or alcohols occurs.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01861J

Reference116 articles.

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