Synthesis of (μ2,η3-allyl-η5-oxapentadienyl)diiron pentacarbonyl complexes, an unusual reaction product from η4-(vinylketene)Fe(CO)3complexes: structure and electron density distribution analysis-Reference-Cited by-同舟云学术

Synthesis of (μ²,η³-allyl-η⁵-oxapentadienyl)diiron pentacarbonyl complexes, an unusual reaction product from η⁴-(vinylketene)Fe(CO)₃complexes: structure and electron density distribution analysis

Published:2023 Issue:9 Volume:52 Page:2722-2734
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Resendiz-Lara Diego A.¹,Rosas-Sánchez Alfredo²³^ORCID,Hashizume Daisuke³^ORCID,Barquera-Lozada José E.⁴^ORCID,Toscano R. Alfredo⁴,López-Cortés José G.⁴^ORCID,Ortega-Alfaro M. Carmen¹^ORCID

Affiliation:

1. Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. México, Mexico

2. Departamento de Química, Centro Universitario de Ciencias Exactas e Ingenierías, Universidad de Guadalajara, Blvd. Marcelino García Barragán #1421, esq. Olímpica, C.P. 44430, Guadalajara, Jalisco, Mexico

3. RIKEN Center for Emergent Matter Science (CEMS), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

4. Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán, C.P. 04510 Cd. México, Mexico

Abstract

We report the unexpected formation of (μ2,η3-allyl-η5-oxapentadienyl)diiron pentacarbonyl complexes 5a–f and an electron density distribution analysis (EDD) for 5e, using High Resolution X-Ray diffraction data in combination with DFT framework.

Funder

Japan Society for the Promotion of Science

Dirección General de Investigación Científica y Técnica

Consejo Nacional de Ciencia y Tecnología

Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03700A

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