Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate

Author:

Soldatova Natalia S.1ORCID,Radzhabov Amirbek D.1ORCID,Ivanov Daniil M.12ORCID,Burguera Sergi3ORCID,Frontera Antonio3ORCID,Abramov Pavel A.14ORCID,Postnikov Pavel S.15ORCID,Kukushkin Vadim Yu.26ORCID

Affiliation:

1. Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Tomsk 634050, Russian Federation

2. Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7/9, Saint Petersburg 199034, Russian Federation

3. Department of Chemistry, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, Palma de Mallorca (Baleares) 07122, Spain

4. Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Av., Novosibirsk 630090, Russian Federation

5. Department of Solid State Engineering, University of Chemical Technology, Prague 16628, Czech Republic

6. Institute of Chemistry and Pharmaceutical Technologies, Altai State University, Barnaul 656049, Russian Federation

Abstract

Iodonium cations recognize the molybdate backbone furnishing “key-to-lock” halogen-bonded supramolecular associates.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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