Anion-induced robust ferroelectricity in sulfurized pseudo-rhombohedral epitaxial BiFeO3 thin films via polarization rotation

Author:

Xi Guoqiang1,Pan Zhao2ORCID,Fang Yue-Wen34ORCID,Tu Jie1,Li Hangren1,Yang Qianqian1,Liu Chen5,Luo Huajie6,Ding Jiaqi7,Xu Shuai2,Deng Shiqing6ORCID,Wang Qingxiao8,Zheng Dongxing5,Long Youwen29ORCID,Jin Kuijuan2ORCID,Zhang Xixiang5ORCID,Tian Jianjun1ORCID,Zhang Linxing1ORCID

Affiliation:

1. Institute for Advanced Materials Technology, University of Science and Technology Beijing, Beijing 100083, China

2. Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

3. Centro de Física de Materiales (CSIC-UPV/EHU), Manuel de Lardizabal pasealekua 5, 20018 Donostia/San Sebastián, Spain

4. Fisika Aplikatua Saila, Gipuzkoako Ingeniaritza Eskola, University of the Basque Country (UPV/EHU), Europa Plaza 1, 20018 Donostia/San Sebastián, Spain

5. Physical Science and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia

6. Beijing Advanced Innovation Center for Materials Genome Engineering, Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, China

7. Key Laboratory for Micro/Nano Optoelectronic Devices of Ministry of Education, School of Physics and Electronics, Hunan University, Changsha 410082, China

8. Corelab, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia

9. Songshan Lake Materials Laboratory, Dongguan, Guangdong 523808, China

Abstract

A feasible anion engineering strategy by introducing sulfur anions in BiFeO3 epitaxial thin films, resulting in a driven polarization rotation for robust ferroelectricity.

Funder

Chinese Academy of Sciences

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

National Program for Support of Top-notch Young Professionals

National Key Research and Development Program of China

Beijing Synchrotron Radiation Facility

Beijing Municipal Natural Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

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