High-temperature decomposition of Cu2BaSnS4 with Sn loss reveals newly identified compound Cu2Ba3Sn2S8-Reference-Cited by-同舟云学术

High-temperature decomposition of Cu2BaSnS4 with Sn loss reveals newly identified compound Cu2Ba3Sn2S8

Published:2020 Issue:22 Volume:8 Page:11346-11353
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Márquez José A.¹²³^ORCID,Sun Jon-Paul⁴⁵⁶⁷,Stange Helena¹²³,Ali Hasan⁸⁹¹⁰¹¹¹²,Choubrac Leo¹²³,Schäfer Stefan¹²³,Hages Charles J.¹²³¹³¹⁴,Leifer Klaus⁸⁹¹⁰¹¹¹²^ORCID,Unold Thomas¹²³^ORCID,Mitzi David B.⁴⁵⁶⁷¹⁵^ORCID,Mainz Roland¹²³^ORCID

Affiliation:

1. Helmholtz-Zentrum Berlin für Materialien und Energie GmbH

2. 14109 Berlin

3. Germany

4. Department of Mechanical Engineering and Materials Science

5. Duke University

6. Durham

7. USA

8. Division of Applied Materials Sciences

9. Department of Engineering Sciences

10. Angstrom Laboratory

11. Uppsala University

12. SE 752 37 Uppsala

13. University of Florida

14. Department of Chemical Engineering

15. Department of Chemistry

Abstract

The decomposition mechanism of Cu₂BaSnS₄ is studied by in situ diffraction and fluorescence analysis revealing “Sn loss” and Cu₂Ba₃Sn₂S₈ at high temperatures.

Funder

U.S. Department of Energy

Basic Energy Sciences

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/TA/D0TA02348E

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