Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex-Reference-Cited by-同舟云学术

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Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex

Published:2020 Issue:6 Volume:11 Page:1683-1690
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Fisher Katherine J.¹²³⁴,Feuer Margalit L.¹²³⁴,Lant Hannah M. C.¹²³⁴,Mercado Brandon Q.¹²³⁴,Crabtree Robert H.¹²³⁴^ORCID,Brudvig Gary W.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Yale University

3. New Haven

4. USA

Abstract

A high-valent nickel(III) compound performs fast concerted proton–electron transfer on O–H and C–H bonds. Thermodynamic analysis suggests that the oxidizing power of the compound and the formation of a strong ligand O–H bond lead to high reactivity.

Funder

Basic Energy Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC05565G

Reference49 articles.

1. Mechanism of Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes

2. Oxidizing species in the mechanism of cytochrome P450

3. Proton-Coupled Electron Transfer

4. Pivotal Role and Regulation of Proton Transfer in Water Oxidation on Hematite Photoanodes

5. Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities

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1. A Simple Evaluation of Adiabatic Proton Tunneling across the Electrified Double Layer;The Journal of Physical Chemistry C;2024-07-17

2. Functional Model of Compound II of Cytochrome P450: Spectroscopic Characterization and Reactivity Studies of a Fe^IV–OH Complex;JACS Au;2024-03-11

3. Experimental and Computational Determination of a M–Cl Homolytic Bond Dissociation Free Energy: Mn(III)Cl-Mediated C–H Cleavage and Chlorination;Journal of the American Chemical Society;2023-06-06

4. Ligand Tuning in Cu(pyalk)2 Water Oxidation Electrocatalysis;Inorganics;2023-05-26

5. Structural and Spectroscopic Characterization of Copper(III) Complexes and Subsequent One-Electron Oxidation Reaction and Reactivity Studies;Inorganic Chemistry;2023-03-27

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