Cobalt(iii)-catalyzed C–H halogenation of 6-arylpurines: facile entry into arylated, sulfenylated and alkoxylated 6-arylpurines

Author:

Pawar Amit B.1234,Lade Dhanaji M.12345

Affiliation:

1. Division of Natural Product Chemistry

2. CSIR-Indian Institute of Chemical Technology

3. Hyderabad 500007

4. India

5. Academy of Scientific and Innovative Research (AcSIR)

Abstract

Cp*Co(iii)-catalyzed C–H halogenation of 6-arylpurines has been reported under mild conditions and this protocol was further applied for the synthesis of arylated, sulfenylated and alkoxylated purine analogues.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference80 articles.

1. Aryl and Heteroaryllithium Compounds by Metal - Halogen Exchange. Synthesis of Carbocyclic and Heterocyclic Systems

2. M. R. Crampton , Organic Reaction Mechanisms, Wiley, New York, 2003, p. 275

3. Metal Catalyzed Cross Coupling Reactions, ed. F. Dieterich and P. Stang, Wiley-VCH, New York, 1998

4. Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

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