Supermetal: SbF5-mediated methane oxidation occurs by C–H activation and isobutane oxidation occurs by hydride transfer
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. Brigham Young University
3. Provo
4. USA
5. Hyconix
6. Inc.
7. Warrenville
8. Department of Chemistry
9. The Scripps Research Institute
10. Jupiter
Abstract
SbVF5 is generally assumed to oxidize methane through a methanium-to-methyl cation mechanism.
Funder
U.S. Department of Energy
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03564H
Reference39 articles.
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3. Electrophilic reactions at single bonds. III. H-D exchange and protolysis (deuterolysis) of alkanes with superacids. The mechanism of acid-catalyzed hydrocarbon transformation reactions involving the .sigma. electron pair donor ability of single bonds via three-center bond formation
4. Electrophilic reactions at single bonds. XII. Hydrogen-deuterium exchange, protolysis (deuterolysis), and oligocondensation of alkanes with superacids
5. The Alkane σ-Bond Basicity Scale Revisited
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