Ultrafast deactivation of bilirubin: dark intermediates and two-photon isomerization-Reference-Cited by-同舟云学术

Ultrafast deactivation of bilirubin: dark intermediates and two-photon isomerization

Published:2016 Issue:10 Volume:18 Page:7148-7155
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Carreira-Blanco Carlos¹²³⁴,Singer Patrick⁵⁶⁷⁸,Diller Rolf⁵⁶⁷⁸,Luis Pérez Lustres J.¹²³⁴

Affiliation:

1. Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Department of Physical Chemistry

2. Universidade de Santiago de Compostela

3. E-15782 Santiago de Compostela

4. Spain

5. Fachbereich Physik

6. Technische Universität Kaiserslautern

7. D-67663 Kaiserslautern

8. Germany

Abstract

The Franck-Condon state A couples to the dark intermediate B, which shows tight molecular skeleton and distorted hydrogen bonding. B deactivates with nearly 100% efficiency. 2-Photon excitation at 400 nm triggers Z,E isomerization efficiently.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP06971H

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