Selective methane photooxidation into methanol under mild conditions promoted by highly dispersed Cu atoms on crystalline carbon nitrides

Author:

da Silva Marcos A. R.12ORCID,Gil Jéssica C.12,Tarakina Nadezda V.3,Silva Gelson T. S. T.12ORCID,Filho José B. G.4,Krambrock Klaus5,Antonietti Markus3ORCID,Ribeiro Caue2ORCID,Teixeira Ivo F.13ORCID

Affiliation:

1. Department of Chemistry, Federal University of São Carlos, 13565-905, São Carlos, SP, Brazil

2. National Nanotechnology Laboratory for Agriculture, Brazilian Agriculture Research Corporation (Embrapa), XV de Novembro Street – 1452, São Carlos, Brazil

3. Department of Colloid Chemistry, Max Planck Institute of Colloids and Interfaces, Am Mühlenberg 1, D-14476 Potsdam, Germany

4. Department of Chemistry, Federal University of Minas Gerais, Belo Horizonte, Minas Gerais 35400-000, Brazil

5. Department of Physics, Federal University of Minas Gerais, 31270-901, Belo Horizonte, Minas Gerais, Brazil

Abstract

Here we report a new record of the selective methane photooxidation into methanol under mild conditions promoted by highly dispersed Cu atoms on crystalline carbon nitride, it displayed a remarkable methanol production (2900 μmol g−1) in 4 hours.

Funder

Alexander von Humboldt-Stiftung

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Fundação de Amparo à Pesquisa do Estado de São Paulo

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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