How coverage influences thermodynamic and kinetic isotope effects for H2/D2 dissociative adsorption on transition metals-Reference-Cited by-同舟云学术

How coverage influences thermodynamic and kinetic isotope effects for H2/D2 dissociative adsorption on transition metals

Published:2020 Issue:3 Volume:10 Page:671-689
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Chen Benjamin W. J.¹²³⁴^ORCID,Mavrikakis Manos¹²³⁴^ORCID

Affiliation:

1. Department of Chemical and Biological Engineering

2. University of Wisconsin – Madison

3. Madison

4. USA

Abstract

Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/C9CY02338K

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