Remarkable resilience of the formate cage in a multiferroic metal organic framework material: dimethyl ammonium manganese formate (DMAMnF)
Author:
Affiliation:
1. High Pressure & Synchrotron Radiation Physics Division
2. Bhabha Atomic Research Centre
3. Mumbai
4. India
5. Institute of low temperature and structure research
6. Polish Academy of Sciences
7. Poland
8. Homi Bhabha National Institute
Abstract
Shrinking of the cavity formed by the MnO6 octahedra and formate linkers, initiates the distortion of the formate network in DMAMnF and results in ordering of the DMA+ cation, leading to a crystal to crystal phase transition at high pressure.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03080D
Reference45 articles.
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