Prediction of high bond-order metal–metal multiple-bonds in heterobimetallic 3d–4f/5f complexes [TM–M{N(o-[NCH2P(CH3)2]C6H4)3}] (TM = Cr, Mn, Fe; M = U, Np, Pu, and Nd)-Reference-Cited by-同舟云学术

Prediction of high bond-order metal–metal multiple-bonds in heterobimetallic 3d–4f/5f complexes [TM–M{N(o-[NCH2P(CH3)2]C6H4)3}] (TM = Cr, Mn, Fe; M = U, Np, Pu, and Nd)

Published:2019 Issue:34 Volume:48 Page:12867-12879
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hu Shu-Xian¹²³⁴⁵^ORCID,Lu Erli⁶⁷⁸⁹,Liddle Stephen T.⁶⁷⁸⁹^ORCID

Affiliation:

1. Department of Physics

2. University of Science and Technology Beijing

3. Beijing 100083

4. China

5. Beijing Computational Science Research Center

6. School of Chemistry and Centre for Radiochemistry Research

7. The University of Manchester

8. Manchester M13 9PL

9. UK

Abstract

A relativistic quantum chemical study on hypothetical but potentially experimentally realisable TM–actinide and –neodymium complexes reveals the similarity in their structures but the differences in the multiplicity of the metal–metal bonds.

Funder

Foundation of President of China Academy of Engineering Physics

National Natural Science Foundation of China

University of Manchester

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03086G

Reference87 articles.

1. F. A. Cotton , C. A.Murillo and R. A.Walton , Multiple Bonds Between Metal Atoms , Springer , New York , 3rd edn, 2005