Enhanced association for C70 over C60 with a metal complex with corannulene derivate ligands
Author:
Affiliation:
1. GIR-MIOMeT-IU CINQUIMA/Química Inorgánica
2. Facultad de Ciencias
3. Universidad de Valladolid
4. Valladolid, Spain
5. Química-Física y Química Inorgánica
Abstract
The geometry imposed by the coordination sphere around the metal, together with the choice of the “arms” can be advantageously used to build corannulene-based molecular tweezers, which show great affinities for C60 and C70, as revealed by NMR titration experiments.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02078B
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