Asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B-Reference-Cited by-同舟云学术

Asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B

Published:2021 Issue:13 Volume:12 Page:4747-4752
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lu Xiao-Long¹²³⁴⁵,Qiu Yuanyou¹²³⁴⁵,Yang Baochao¹²³⁴⁵,He Haibing⁶³⁴⁵^ORCID,Gao Shuanhu¹²³⁴⁵^ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes

2. School of Chemistry and Molecular Engineering

3. East China Normal University

4. Shanghai 200062

5. China

6. Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development

Abstract

The asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B was achieved in 6–7 steps using an easily accessible meso-cyclohexadienone derivative.

Funder

National Natural Science Foundation of China

Science and Technology Commission of Shanghai Municipality

Shanghai Education Development Foundation

Fundamental Research Funds for the Central Universities

Program of Shanghai Academic Research Leader

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC07089K

Reference76 articles.

1. Chemical and Biological Aspects of Marine Sponges of the Genus Xestospongia

2. Halenaquinone, a pentacyclic polyketide from a marine sponge

3. Total synthesis of (+)-halenaquinol and (+)-halenaquinone. Experimental proof of their absolute stereostructures theoretically determined

4. Catalytic Asymmetric Synthesis of Halenaquinone and Halenaquinol

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