Exploring the chemical dynamics of phenanthrene (C14H10) formation via the bimolecular gas-phase reaction of the phenylethynyl radical (C6H5CC) with benzene (C6H6)-Reference-Cited by-同舟云学术

Exploring the chemical dynamics of phenanthrene (C₁₄H₁₀) formation via the bimolecular gas-phase reaction of the phenylethynyl radical (C₆H₅CC) with benzene (C₆H₆)

Published:2024 Issue: Volume:251 Page:509-522
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Goettl Shane J.¹^ORCID,Yang Zhenghai¹,He Chao¹^ORCID,Somani Ankit²,Portela-Gonzalez Adrian²,Sander Wolfram²^ORCID,Mebel Alexander M.³^ORCID,Kaiser Ralf I.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Hawaii at Manoa, Honolulu, Hawaii 96822, USA

2. Lehrstuhl für Organische Chemie II, Ruhr-Universität Bochum, 44801 Bochum, Germany

3. Department of Chemistry and Biochemistry, Florida International University, Miami, Florida 33199, USA

Abstract

The phenylethynyl radical reaction with benzene leads to the barrierless, gas-phase synthesis of phenanthrene under single collision conditions as a new pathway toward the formation of polycyclic aromatic hydrocarbons in deep space.

Funder

Basic Energy Sciences

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/FD/D3FD00159H

Reference44 articles.

1. Formation and growth mechanisms of polycyclic aromatic hydrocarbons: A mini-review

2. A. G. G. M.Tielens , in Dust and Chemistry in Astronomy , ed. D. A. Williams and T. J. Millar , Institute of Physics Publishing , Bristol, UK , 1993 , pp. 99–136

3. S.Schlemmer , T.Giesen , H.Mutschke and C.Jäger , Laboratory Astrochemistry: from Molecules through Nanoparticles to Grains , Wiley-VCH , Singapore , 2014

4. Organic Molecules in the Interstellar Medium, Comets, and Meteorites: A Voyage from Dark Clouds to the Early Earth

5. Interstellar Polycyclic Aromatic Hydrocarbon Molecules