Thermodynamics and kinetics of protonated merocyanine photoacids in water-Reference-Cited by-同舟云学术

Thermodynamics and kinetics of protonated merocyanine photoacids in water

Published:2020 Issue:32 Volume:11 Page:8457-8468
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Berton Cesare¹²³⁴^ORCID,Busiello Daniel Maria⁵²³⁴^ORCID,Zamuner Stefano⁵²³⁴,Solari Euro¹²³⁴,Scopelliti Rosario¹²³⁴^ORCID,Fadaei-Tirani Farzaneh¹²³⁴^ORCID,Severin Kay¹²³⁴^ORCID,Pezzato Cristian¹²³⁴^ORCID

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques

2. École Polytechnique Fédérale de Lausanne (EPFL)

3. 1015 Lausanne

4. Switzerland

5. Institut de Physique

Abstract

We rationalize the behaviour of protonated merocyanines in water through cross-validation of ¹H NMR, UV-Vis and pH measurements, and show their capability to act as reversible photoacids along light/dark cycles can be described by a four-state model.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03152F

Reference87 articles.

1. Proton gradients at the origin of life

2. Functions of a New Photoreceptor Membrane

3. Bacteriorhodopsin Is a Powerful Light-Driven Proton Pump