Scaffold-based [Fe]-hydrogenase model: H2 activation initiates Fe(0)-hydride extrusion and non-biomimetic hydride transfer-Reference-Cited by-同舟云学术

Scaffold-based [Fe]-hydrogenase model: H2 activation initiates Fe(0)-hydride extrusion and non-biomimetic hydride transfer

Published:2021 Issue:38 Volume:12 Page:12838-12846
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kerns Spencer A.¹^ORCID,Seo Junhyeok²^ORCID,Lynch Vincent M.¹,Shearer Jason³,Goralski Sean T.¹,Sullivan Eileen R.¹,Rose Michael J.¹^ORCID

Affiliation:

1. Department of Chemistry, The University of Texas at Austin, Austin, Texas 78712, USA

2. Department of Chemistry, Gwangju Institute of Science and Technology, Gwangju 61005, Republic of Korea

3. Department of Chemistry, Trinity University, One Trinity Place, San Antonio, Texas 78212, USA

Abstract

We report the synthesis and reactivity of a model of [Fe]-hydrogenase derived from an anthracene-based scaffold that includes the endogenous, organometallic acyl(methylene) donor.

Funder

Welch Foundation

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC03154B

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