Synthesis and thermal properties of the heterometallic nickel–ruthenium complex: a potential precursor for catalytically active nanosized Ni

Synthesis and thermal properties of the heterometallic nickel–ruthenium complex: a potential precursor for catalytically active nanosized Ni–Ru alloy

Published:2022 Issue:39 Volume:46 Page:19009-19017
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Filatov E. Yu¹^ORCID,Borodin A. O.¹,Kuratieva N. V.¹,Plusnin P. E.¹^ORCID,Urlukov A. S.²³,Potemkin D. I.²,Korenev S. V.¹,Kostin G. A.¹^ORCID

Affiliation:

1. Nicolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, 630090, Russia

2. Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia

3. Novosibirsk State University, Novosibirsk, 630090, Russia

Abstract

Thermal decomposition of the novel heterometallic complex [RuNO(NO2)4OHNi(En)2] results in a single-phase metastable solid solution Ni0.5Ru0.5. The catalytic activity of the prepared nanoalloy in the CO methanation reaction was demonstrated.

Funder

Russian Science Foundation

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ03402F

Reference50 articles.

1. Investigation of ruthenium promoted palladium catalysts for methanol electrooxidation in alkaline media

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3. Surface noble metal modified PdM/C (M = Ru, Pt, Au) as anode catalysts for direct ethanol fuel cells

4. Ruthenium–Platinum Catalysts and Direct Methanol Fuel Cells (DMFC): A Review of Theoretical and Experimental Breakthroughs

5. Stability of Pt-Ru Alloy for Anode Catalyst in PEFC Fuel Cell: A Density Functional Theory Study

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