Synthesis of pyridine trans-tetrafluoro-λ6-sulfane derivatives via radical addition

Author:

Das Prajwalita1234,Takada Masahiro1234,Tokunaga Etsuko1234ORCID,Saito Norimichi56784,Shibata Norio1234ORCID

Affiliation:

1. Department of Nanopharmaceutical Sciences

2. Nagoya Institute of Technology

3. Nagoya 466-8555

4. Japan

5. Pharmaceutical Division

6. Ube Industries

7. Ltd.

8. Tokyo 105-8449

Abstract

Pyridine-trans-SF4-alkenes or -alkanes have been synthesized for the first time via the radical addition reactions of pyridine-trans-SF4Cl to alkynes or alkenes in good to high yields.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference70 articles.

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2. J. Drabowicz , in Chemistry of Hypervalent Compounds , ed. K. Akiba , Wiley-VCH , New York , 1999 , ch. 7, pp. 211–240

3. N. Furukawa and S.Sato , in Organosulfur Chemistry II , ed. P. C. B. Page , Springer , Berlin, Heidelberg , 1999 , pp. 88–129

4. Chemistry of Four-Membered Ring Compounds Containing a Hypervalent Sulfur Atom and a Heteroatom at the Neighbor Positions

5. and isomers of bis (perfluoroalkyl) sulfur tetrafluorides

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