Copper-catalyzed intramolecular dearomative aza-Wacker reaction of indole-Reference-Cited by-同舟云学术

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Copper-catalyzed intramolecular dearomative aza-Wacker reaction of indole

Published:2024 Issue:28 Volume:60 Page:3858-3861
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Bi¹,Liang Ren-Xiao¹^ORCID,Shen Zhen-Lu¹^ORCID,Jia Yi-Xia¹²^ORCID

Affiliation:

1. College of Chemical Engineering, State Key Laboratory Breeding Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Chaowang Road #18, Hangzhou 310014, China

2. School of Chemistry and Chemical Engineering, Tianjin University of Technology, China

Abstract

A copper-catalyzed intramolecular dearomative amination of indoles via a formal aza-Wacker reaction is described, affording polycyclic indolines bearing exocyclic CC bonds in moderate to excellent yields with molecular oxygen as an oxidant.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Fundamental Research Funds for the Provincial Universities of Zhejiang

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC06217A

Reference52 articles.

1. Stereoselective and Regioselective Synthesis of Heterocycles via Copper-Catalyzed Additions of Amine Derivatives and Alcohols to Alkenes

2. Evolution of copper(II) as a new alkene amination promoter and catalyst

3. Intramolecular aminopalladation of alkenes as a key step to pyrrolidines and related heterocycles

4. Synthesis of Heterocycles via Palladium-Catalyzed Oxidative Addition

5. Metal-Initiated Amination of Alkenes and Alkynes

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