Mechanistic studies of 1,3-dipolar cycloadditions of bicyclic thioisomünchnones with alkenes. A computational rationale focused on donor–acceptor interactions
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica
2. Facultad de Ciencias-UEX
3. IACYS-Unidad de Química Verde y Desarrollo Sostenible
4. E-06006 Badajoz
5. Spain
6. Department of Chemistry
7. University of Southampton
8. Southampton SO17 1BJ
9. UK
Abstract
Unlike monocyclic mesoionic dipoles, bicyclic thioisomünchnones provide high levels of regio- and stereoselection leading to heteroatom-rich polycycles.
Funder
European Regional Development Fund
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB00683K
Reference48 articles.
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2. Asymmetric 1,3-dipolar cycloadditions
3. H. Suga and K.Itoh , in Methods and Applications of Cycloaddition Reactions in Organic Syntheses , ed. N. Nishiwaki , John Wiley & Sons , Hoboken, New Jersey , 2013 , pp. 175–204
4. Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions
5. Progress in 1,3-dipolar cycloadditions in the recent decade: an update to strategic development towards the arsenal of organic synthesis
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