Phosphine-catalyzed dearomative (3 + 2) annulation of 2-nitrobenzofurans and nitrobenzothiophenes with allenoates-Reference-Cited by-同舟云学术

Phosphine-catalyzed dearomative (3 + 2) annulation of 2-nitrobenzofurans and nitrobenzothiophenes with allenoates

Published:2019 Issue:21 Volume:17 Page:5294-5304
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhao Jian-Qiang¹²³⁴^ORCID,Yang Lei⁵⁶⁷⁸⁴,You Yong¹²³⁴,Wang Zhen-Hua¹²³⁴^ORCID,Xie Ke-Xin⁹⁷¹⁰⁴,Zhang Xiao-Mei⁵⁶⁷⁸⁴^ORCID,Xu Xiao-Ying⁵⁶⁷⁸⁴,Yuan Wei-Cheng⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Institute for Advanced Study

2. Chengdu University

3. Chengdu 610106

4. China

5. National Engineering Research Center of Chiral Drugs

6. Chengdu Institute of Organic Chemistry

7. Chinese Academy of Sciences

8. Chengdu

9. Chengdu Institute of Biology

10. Chengdu 610041

Abstract

An efficient Ph₂PMe-catalyzed dearomative (3 + 2) annulation of 2-nitrobenzofurans, 2-nitrobenzothiophenes, and 3-nitrobenzothiophenes with allenoates is reported.

Funder

National Natural Science Foundation of China

Sichuan Youth Science and Technology Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00775J

Reference120 articles.

1. Transition-Metal-Mediated Dearomatization Reactions

2. Nucleophilic Dearomatizing (DNAr) Reactions of Aromatic C,H-Systems. A Mature Paradigm in Organic Synthesis