Enantioselective synthesis of tunable chiral pyridine–aminophosphine ligands and their applications in asymmetric hydrogenation
Author:
Affiliation:
1. Beijing National Laboratory for Molecular Sciences
2. CAS Key Laboratory of Molecular Recognition and Function
3. Institute of Chemistry
4. Chinese Academy of Sciences (CAS)
5. and University of Chinese Academy of Sciences
Abstract
A small library of tunable chiral pyridine–aminophosphine ligands were synthesized based on tetrahydroquinoline scaffolds obtained via Ru-catalyzed asymmetric hydrogenation. The ligands were applied in the Ir-catalyzed asymmetric hydrogenation of olefins and imines.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00770A
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