Pore size effects on high-efficiency proton conduction in three stable 3D Al-based MOFs modified with imidazole-Reference-Cited by-同舟云学术

Pore size effects on high-efficiency proton conduction in three stable 3D Al-based MOFs modified with imidazole

Published:2023 Issue:24 Volume:10 Page:7359-7368
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhang Lu¹,Ma Xiaoxue¹,Li Xin¹,Liu Ronghua¹,Zhao Xin¹,Hao Hongguo¹^ORCID,Yan Hui¹,Zhu Hongjie¹,Zhou Huawei¹^ORCID,Zhong Dichang²

Affiliation:

1. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, School of Pharmacy, Liaocheng University, Liaocheng 252059, China

2. Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology, Tianjin 300384, China

Abstract

Three stable porous aluminum-based MOFs 1–3 with different pore sizes were selected as an imidazole (Im) supporter and three proton conductive composites Im@1–3 were prepared. Due to the pore size effect, the σ value of Im@3 can be up to 2.55 × 10−1 S cm−1 at 80 °C and 100% RH.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Liaocheng University

Project of Shandong Province Higher Educational Science and Technology Program

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI01941A

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